Molecular magnetic properties of a dysprosium(III) complex coordinated to a nonadentate bispidine ligand
نویسندگان
چکیده
Abstract The Dy III complex of the nonadentate bispidine L 1 (bispidine=3,7‐diazabicyclo[3.3.1]nonane) has a capped square antiprismatic structure, known to lead suppressed quantum relaxation magnetization by tunneling. [Dy ]OTf indeed is an SMM with modest barrier relaxation. experimentally determined 46 cm −1 confirmed ab initio calculations (43.5 ), and quantum‐chemical analysis indicates that ligand modifications, leading higher symmetry stronger axial field should significantly increase effective
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ژورنال
عنوان ژورنال: Zeitschrift für anorganische und allgemeine Chemie
سال: 2021
ISSN: ['0044-2313', '1521-3749']
DOI: https://doi.org/10.1002/zaac.202000475